What is polymeric MDI used for?
Polymeric MDIs are generally used in manufacturing rigid and semi-rigid polyurethane foam for construction panels, spray-on insulation, refrigeration insulation, and automotive interior panels.
What is a polymeric MDI?
Polymeric MDI (PMDI), the primary technical/commercial form of MDI, is actually a mixture that contains 25-80% monomeric 4,4′-MDI as well as oligomers containing 3-6 rings and other minor isomers, such as the 2,2′-isomer. The exact composition of PMDI varies with the manufacturer.
What is MDI in polyurethane?
What Is MDI? Methylenediphenyl diisocyanate (MDI) is used in the production of polyurethanes for many applications, including the manufacture of rigid polyurethane foams used for home and refrigerator insulation. Insulation made with MDI can help consumers conserve energy.
Does MDI react with water?
When MDI is added to water, its NCO groups react readily with OH groups of the water to form mixtures of diisocyanates and amines, which then readily react with more MDI to produce inert, solid, insoluble polyurea (EU, 1999).
What is MDI in asthma?
Inhaled respiratory medications are often taken by using a device called a metered dose inhaler, or MDI. The MDI is a pressurized canister of medicine in a plastic holder with a mouthpiece. When sprayed, it gives a reliable, consistent dose of medication.
Why is MDI in short supply?
The North American MDI continues to be disrupted due to raw materials shortages and prices are firming once again. The surge in prices is due to lack of supply availability, even though most plants are reported to be online.
Are there any studies on exposure to MDI?
Several studies of polyurethane foam workers examined the role of exposure to isocyanates in relation to cancer incidence and mortality. In these studies, PMDI/MDI was one of a variety of substances in the work environment. Thus, these studies are inadequate for categorizing the carcinogenic potential of MDI.
What does MDI react with in the air?
MDI reacts with acids, alcohols, basic materials (e.g., sodium hydroxide, ammonia, and amines), magnesium and aluminum (and their alloys), metal salts (e.g., tin, iron, aluminum, and zinc chlorides), strong oxidizing agents (e.g.,
Who are the manufacturers of MDI and TDI?
D C Allport, D S Gilbert and BTury Manufacture of MDI 277 Manufacture of TDI 280 Modified MDI and TDI 282 Reading 284 5.2 Structures and nomenclature 285
What happens to MDI in water filled containers?
MDI is denser than water and will therefore sink to the bottom of water-filled containers. Although it reacts with water, the rate of reaction is very slow at temperatures below 122°F (50°C). At higher temperatures or in the presence of catalysts/basic materials, the reaction becomes progressively more vigorous and can become violent.